|
|
3-oxo-23,24-bisnorchol-4-en-22-oic_acid-CoA + acceptor <=> 3-oxo-23,24-bisnorchol-4,17(20)-dien-22-oyl-CoA + reduced_acceptor
|
1.3.99
|
–
|
|
MetaCyc:
RXN-12743
|
|
|
|
24-hydroxy-3-oxocholest-4-en-26-oyl-CoA <=> 22-oxocholest-4-en-3-one + propionyl-CoA
|
not assigned
|
–
|
|
MetaCyc:
RXN-21469
|
|
|
|
17-hydroxy-3-oxo-4-pregnane-20-carboxyl-CoA <=> 4-androstene-3,17-dione + propionyl-CoA
|
2.3.1
|
–
|
|
MetaCyc:
RXN-12745
|
|
|
|
3,23-dioxo-23,24-bisnorchol-4-ene + H2O + NAD+ <=> 23,24-bisnorcholesta-4-ene-22-oic_acid + NADH + H+
|
1.2.1
|
–
|
|
MetaCyc:
RXN-21474
|
|
|
|
(25R)-26-hydroxycholest-4-en-3-one + acceptor <=> (25R)-26-oxocholest-4-en-3-one + reduced_acceptor
|
not assigned
|
–
|
|
MetaCyc:
RXN-21458
|
|
|
|
(25S)-3-oxocholest-4-en-26-oyl-CoA <=> (25R)-3-oxocholest-4-en-26-oyl-CoA
|
5.1.99.4
alpha-methylacyl-CoA racemase
|
–
|
|
MetaCyc:
RXN-17645
|
|
|
|
cholesterol + NAD+ <=> 5-Cholesten-3-one + NADH + H+
|
1.1.1.145
3beta-hydroxy-Delta5-steroid dehydrogenase
|
–
|
|
BRENDA:
BS396694
MetaCyc:
RXN-12693
|
|
|
|
22-hydroxy-3-oxochol-4-en-24-oyl-CoA <=> 3-oxochol-4,22-dien-24-oyl-CoA + H2O
|
4.2.1
|
–
|
|
MetaCyc:
RXN-12708
|
|
|
|
3-oxochol-4-en-24-oate + ATP + CoA <=> 3-oxochol-4-en-24-oyl-CoA + AMP + diphosphate
|
6.2.1
|
–
|
|
MetaCyc:
RXN-21471
|
|
|
|
25-hydroxycholest-4-en-3-one <=> (25R)-26-hydroxycholest-4-en-3-one
|
not assigned
|
–
|
|
MetaCyc:
RXN-21457
|
|
|
|
cholest-4-en-3-one + H2O + acceptor <=> 25-hydroxycholest-4-en-3-one + reduced_acceptor
|
1.17.99.e
|
–
|
|
MetaCyc:
RXN-21430
|
|
|
|
(25R)-3-oxocholest-4-en-26-oate <=> (25R)-3-oxocholest-4-en-26-oate
|
not assigned
|
–
|
|
MetaCyc:
TRANS-RXN-406
|
|
|
|
22-hydroxy-3-oxochol-4-en-24-oyl-CoA <=> 3,23-dioxo-23,24-bisnorchol-4-ene + acetyl-CoA
|
not assigned
|
–
|
|
MetaCyc:
RXN-21472
|
|
|
|
22-oxocholest-4-en-3-one + H2O + NAD+ <=> 3-oxochol-4-en-24-oate + NADH + H+
|
1.2.1
|
–
|
|
MetaCyc:
RXN-21470
|
|
|
|
17-hydroxy-3-oxo-4-pregnane-20-carboxyl-CoA <=> 3-oxo-23,24-bisnorchol-4,17(20)-dien-22-oyl-CoA + H2O
|
4.2.1
|
–
|
|
MetaCyc:
RXN-12744
|
|
|
|
24-hydroxy-3-oxocholest-4-en-26-oyl-CoA <=> 3-oxocholest-4,24-dien-26-oyl-CoA + H2O
|
4.2.1
|
–
|
|
MetaCyc:
RXN-12704
|
|
|
|
(25S)-3-oxocholest-4-en-26-oyl-CoA + acceptor <=> 3-oxocholest-4,24-dien-26-oyl-CoA + reduced_acceptor
|
1.3.99
|
–
|
|
MetaCyc:
RXN-12703
|
|
|
|
3-oxochol-4-en-24-oyl-CoA + acceptor <=> 3-oxochol-4,22-dien-24-oyl-CoA + reduced_acceptor
|
1.3.99
|
–
|
|
MetaCyc:
RXN-12707
|
|
|
|
(25R)-3-oxocholest-4-en-26-oate + ATP + CoA <=> (25R)-3-oxocholest-4-en-26-oyl-CoA + AMP + diphosphate
|
6.2.1.42
3-oxocholest-4-en-26-oate---CoA ligase
|
–
|
|
MetaCyc:
RXN-17650
|
|
|
|
(25R)-26-oxocholest-4-en-3-one + H2O + NAD+ <=> (25R)-3-oxocholest-4-en-26-oate + NADH + H+
|
1.2.1
|
–
|
|
MetaCyc:
RXN-21459
|
|
|
|
23,24-bisnorcholesta-4-ene-22-oic_acid + ATP + CoA <=> 3-oxo-23,24-bisnorchol-4-en-22-oic_acid-CoA + AMP + diphosphate
|
6.2.1
|
–
|
|
MetaCyc:
RXN-21475
|
|
|
|
5-Cholesten-3-one <=> cholest-4-en-3-one
|
5.3.3.1
steroid Delta-isomerase
|
–
|
|
BRENDA:
BS1075
MetaCyc:
RXN-12694
|
|